Photoinitiated solid-state [2+2] cycloaddition reaction in [Zn2(H2O)2(2-Amal)2(bpe)] (2-Amal = 2-allylmalonate) crystal
نویسندگان
چکیده
منابع مشابه
Solid-state polymerization in a polyrotaxane coordination polymer via a [2+2] cycloaddition reaction.
Alternate bpeb ligands in the polyrotaxane 2D coordination polymer [Cd(bpeb)(sdb)]·DMA (1) selectively undergo polymerization via a [2+2] cycloaddition reaction to form a polyrotaxane based 3D structure [Cd(bpeb)0.5(poly-bppcb)0.5(sdb)]·DMA (2) in a single-crystal-to-single-crystal manner.
متن کاملSingle-crystal to single-crystal transformation of 1D coordination polymer via photochemical [2+2] cycloaddition reaction.
Photochemical single-crystal to single-crystal transformation of one 1D polymer [Cd(bpe)(CBA)(2)](n) afforded a new 1D polymer [Cd(rctt-tpcb)(0.5)(CBA)(2)](n) which underwent hydrothermal reaction in strong acidic solution to form a 3D coordination polymer {[Cd(rtct-tpcb)Cl(2)]·2H(2)O}(n).
متن کاملSolid-state conversion of a MOF to a metal-organo polymeric framework (MOPF) via [2+2] cycloaddition reaction.
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal-organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
متن کاملPhotochemical [2 + 2] cycloaddition as a tool to study a solid-state structural transformation.
The solid-state structural transformation of the hydrogen-bonded 1D coordination polymer [Cd(bpe)(CH(3)COO)(2)(H(2)O)](n), to a ladder-type structure is evident from a photochemical [2 + 2] cycloaddition reaction forming 100% rctt-cyclobutane isomer.
متن کاملThermally reversible single-crystal to single-crystal transformation of mononuclear to dinuclear Zn(II) complexes by [2+2] cycloaddition reaction.
Two Zn(II) complexes of trans-4-styrylpyridine ligands undergo [2+2] cycloaddition reaction forming Zn(II) complex dimers in a single-crystal to single-crystal (SCSC) manner which were thermally reversible. The dimers are presumed to be the stable intermediates in the formation of 1D coordination polymers upon prolonged exposure to UV light.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2018
ISSN: 2053-2733
DOI: 10.1107/s2053273318089222